ABSTRACT
Nanotechnology is the engineering of functional systems at the molecular scale. This covers both current work and concepts that are more advanced.
In its original sense, 'nanotechnology' refers to the projected ability to construct items from the bottom up, using techniques and tools being developed today to make complete, high performance products.
Nanotechnology, in its traditional sense, means building things from the bottom up, with atomic precision
There are four generations of nanotechnology development:
They are:
· Passive nanostructures
· Active nanostructures
· Systems of nanosystems
· Molecular nanosytems
These generations are explained in detail as we go further.
Nanotechnology also has a conflicting definition i.e conflicting definitions of nanotechnology and blurry distinctions between significantly different fields have complicated the effort to understand the differences and develop sensible, effective policy.
Many researches are being conducted on nanotechnology, some of the researches are as follows : Nanomaterials, Bottom-up approaches, Top-down approaches, Functional approaches, Speculative. These are also explained in detailed.
In this presentation we have also explained about the tools and techniques. There are several important modern developments. The atomic force microscope (AFM) and the Scanning Tunneling Microscope (STM) are two early versions of scanning probes that launched nanotechnology.
Some of the applications of nanotechnology which we have explained further are as follows:
- Medicine
- Chemistry and environment
- Energy
- Information & communication
- Heavy Industry
- Consumer goods
INTRODUCTION
Definition: Nanotechnology is the engineering of functional systems at the molecular scale. This covers both current work and concepts that are more advanced.
Fig :With 15,342 atoms, this parallel-shaft speed reducer gear is one of the largest nanomechanical devices ever modeled in atomic detail.
Nanotechnology is also known as general purpose technology and it is also known to dual-use technology.
General-Purpose Technology
Nanotechnology is sometimes referred to as a general-purpose technology. That's because in its advanced form it will have significant impact on almost all industries and all areas of society. It will offer better built, longer lasting, cleaner, safer, and smarter products for the home, for communications, for medicine, for transportation, for agriculture, and for industry in general.
Dual-Use Technology
Like electricity or computers before it, nanotech will offer greatly improved efficiency in almost every facet of life. But as a general-purpose technology, it will be dual-use, meaning it will have many commercial uses and it also will have many military uses—making far more powerful weapons and tools of surveillance. Thus it represents not only wonderful benefits for humanity, but also grave risks.
Importance:
Using nanotechnology, researchers and manufacturers can fabricate materials literally molecule-by-molecule. They can harness previously inaccessible properties of matter and "custom design" ultra-precise new structures, devices, and systems with new, unique, and often remarkable properties—such as materials with vastly increased strength, vastly decreased weight, vastly greater electrical connectivity, or the ability to change shape or color on demand.
FOUR GENERATIONS:
There are four generations of nanotechnology development:
They are:
· Passive nanostructures
· Active nanostructures
· Systems of nanosystems
· Molecular nanosytems
Passive nanostructures :
Passive nanostructures are the materials designed to perform one task.
The current era is following this.
Active nanostructures :
Active nanostructures are the material designed to perform multitasking.
for example, actuators, drug delivery devices, and sensors.
Systems of nanosystems:
This is expected to begin emerging around 2010 and will feature nanosystems with thousands of interacting components.
Molecular nanosytems:
A few years after third generation nanosystems, the first integrated nanosystems, functioning much like a mammalian cell with hierarchical systems within systems, are expected to be developed
RESEARCHES ON NANOTECHNOLOGY:
Nanomaterials:
This includes subfields which develop or study materials having unique properties arising from their nanoscale dimensions.
- Interface and Colloid Science has given rise to many materials which may be useful in nanotechnology, such as carbon nanotubes and otherfullerenes, and various nanoparticles and nanorods.
- Nanoscale materials can also be used for bulk applications; most present commercial applications of nanotechnology are of this flavor.
- Progress has been made in using these materials for medical applications; see Nanomedicine.
- Nanoscale materials are sometimes used in solar cells which combats the cost of traditional Silicon solar cells
- Development of applications incorporating semiconductor nanoparticles to be used in the next generation of products, such as display technology, lighting, solar cells and biological imaging; see Quantum Dots.
Bottom-up approaches:
These seek to arrange smaller components into more complex assemblies.
- DNA nanotechnology utilizes the specificity of Watson–Crick basepairing to construct well-defined structures out of DNA and other nucleic acids.
- Approaches from the field of "classical" chemical synthesis also aim at designing molecules with well-defined shape (e.g. bis-peptides).
- More generally, molecular self-assembly seeks to use concepts of supramolecular chemistry, and molecular recognition in particular, to cause single-molecule components to automatically arrange themselves into some useful conformation.
Top-down approaches
These seek to create smaller devices by using larger ones to direct their assembly.
- Many technologies that descended from conventional solid-state silicon methods for fabricating microprocessors are now capable of creating features smaller than 100 nm, falling under the definition of nanotechnology. Giant magnetoresistance-based hard drives already on the market fit this description as do atomic layer deposition (ALD) techniques. Peter Grünberg and Albert Fert received the Nobel Prize in Physics for their discovery of Giant magnetoresistance and contributions to the field of spintronics in 2007.
- Solid-state techniques can also be used to create devices known as nanoelectromechanical systems or NEMS, which are related to microelectromechanical systems or MEMS.
- Atomic force microscope tips can be used as a nanoscale "write head" to deposit a chemical upon a surface in a desired pattern in a process called dip pen nanolithography. This fits into the larger subfield of nanolithography.
- Focused ion beams can directly remove material, or even deposit material when suitable pre-cursor gasses are applied at the same time. For example, this technique is used routinely to create sub-100 nm sections of material for analysis in Transmission electron microscopy.
Functional approaches:
These seek to develop components of a desired functionality without regard to how they might be assembled.
- Molecular electronics seeks to develop molecules with useful electronic properties. These could then be used as single-molecule components in a nanoelectronic device. For an example see rotaxane.
- Synthetic chemical methods can also be used to create what forensics call synthetic molecular motors, such as in a so-called nanocar.
Speculative
These subfields seek to anticipate what inventions nanotechnology might yield, or attempt to propose an agenda along which inquiry might progress. These often take a big-picture view of nanotechnology, with more emphasis on its societal implications than the details of how such inventions could actually be created.
- Molecular nanotechnology is a proposed approach which involves manipulating single molecules in finely controlled, deterministic ways. This is more theoretical than the other subfields and is beyond current capabilities.
- Nanorobotics centers on self-sufficient machines of some functionality operating at the nanoscale. There are hopes for applying nanorobots in medicine[17][18][19], but it may not be easy to do such a thing because of several drawbacks of such devices. Nevertheless, progress on innovative materials and methodologies has been demonstrated with some patents granted about new nanomanufacturing devices for future commercial applications, which also progressively helps in the development towards nanorobots with the use of embedded nanobioelectronics concepts.
- Programmable matter based on artificial atoms seeks to design materials whose properties can be easily, reversibly and externally controlled.
- Due to the popularity and media exposure of the term nanotechnology, the words picotechnology and femtotechnology have been coined in analogy to it, although these are only used rarely and informally.
Tools and techniques:
Typical AFM setup. A microfabricated cantilever with a sharp tip is deflected by features on a sample surface, much like in a phonograph but on a much smaller scale. A laser beam reflects off the backside of the cantilever into a set of photodetectors, allowing the deflection to be measured and assembled into an image of the surface.
There are several important modern developments. The atomic force microscope (AFM) and the Scanning Tunneling Microscope (STM) are two early versions of scanning probes that launched nanotechnology.
Another group of nanotechnological techniques include those used for fabrication of nanowires, those used in semiconductor fabrication such as deep ultraviolet lithography, electron beam lithography, focused ion beam machining, nanoimprint lithography, atomic layer deposition, and molecular vapor deposition, and further including molecular self-assembly techniques such as those employing di-block copolymers. However, all of these techniques preceded the nanotech era, and are extensions in the development of scientific advancements rather than techniques which were devised with the sole purpose of creating nanotechnology and which were results of nanotechnology research.
APPLICATIONS
Medicine
The biological and medical research communities have exploited the unique properties of nanomaterials for various applications (e.g., contrast agents for cell imaging and therapeutics for treating cancer). Terms such as biomedical nanotechnology, bionanotechnology, and nanomedicine are used to describe this hybrid field. Functionalities can be added to nanomaterials by interfacing them with biological molecules or structures. The size of nanomaterials is similar to that of most biological molecules and structures; therefore, nanomaterials can be useful for both in vivo and in vitro biomedical research and applications. Thus far, the integration of nanomaterials with biology has led to the development of diagnostic devices, contrast agents, analytical tools, physical therapy applications, and drug delivery vehicles.
Diagnostics
Nanotechnology-on-a-chip is one more dimension of lab-on-a-chip technology. Biological tests measuring the presence or activity of selected substances become quicker, more sensitive and more flexible when certain nanoscale particles are put to work as tags or labels. Magnetic nanoparticles, bound to a suitable antibody, are used to label specific molecules, structures or microorganisms. Gold nanoparticles tagged with short segments of DNA can be used for detection of genetic sequence in a sample. Multicolor optical coding for biological assays has been achieved by embedding different-sized quantum dots into polymeric microbeads. Nanopore technology for analysis of nucleic acids converts strings of nucleotides directly into electronic signatures.
Drug delivery
The overall drug consumption and side-effects can be lowered significantly by depositing the active agent in the morbid region only and in no higher dose than needed. This highly selective approach reduces costs and human suffering. An example can be found in dendrimers and nanoporous materials. They could hold small drug molecules transporting them to the desired location. Another vision is based on small electromechanical systems; NEMS are being investigated for the active release of drugs. Some potentially important applications include cancer treatment with iron nanoparticles or gold shells. A targeted or personalized medicine reduces the drug consumption and treatment expenses resulting in an overall societal benefit by reducing the costs to the public health system. Nanotechnology is also opening up new opportunities in implantable delivery systems, which are often preferable to the use of injectable drugs, because the latter frequently display first-order kinetics (the blood concentration goes up rapidly, but drops exponentially over time). This rapid rise may cause difficulties with toxicity, and drug efficacy can diminish as the drug concentration falls below the targeted range.
Tissue engineering
Nanotechnology can help to reproduce or to repair damaged tissue. "Tissue engineering" makes use of artificially stimulated cell proliferation by using suitable nanomaterial-based scaffolds and growth factors. Tissue engineering might replace today's conventional treatments like organ transplants or artificial implants. Advanced nanotechnology based tissue engineering might lead to some life extension, but not significant amounts--that would require intracellular manipulation of the seven mechanisms of aging, which tissue engineering cannot do.
For patients with end-state organ failure, there may not be enough healthy cells for expansion and transplantation into the ECM (extracellular matrix). In this case, pluripotent stem cells are needed. One potential source for these cells is iPS (induced Pluripontent Stem cells); these are ordinary cells from the patients own body that are reprogrammed into a pluripotent state, and has the advantage of avoiding rejection (and the potentially life-threatening complications associated with immunosuppressive treatments). Another potential source of pluripotent cells is from embryos, but this has two disadvantages: 1) It requires that we solve the problem of cloning, which is technically very difficult (especially preventing abnormalities). 2) It requires the harvesting of embryos. Given that each one of us was once an embryo, this source is ethically problematic.
Chemistry and environment
Chemical catalysis and filtration techniques are two prominent examples where nanotechnology already plays a role. The synthesis provides novel materials with tailored features and chemical properties: for example, nanoparticles with a distinct chemical surrounding (ligands), or specific optical properties. In this sense, chemistry is indeed a basic nanoscience. In a short-term perspective, chemistry will provide novel "nanomaterials" and in the long run, superior processes such as "self-assembly" will enable energy and time preserving strategies. In a sense, all chemical synthesis can be understood in terms of nanotechnology, because of its ability to manufacture certain molecules. Thus, chemistry forms a base for nanotechnology providing tailor-made molecules, polymers, etcetera, as well as clusters and nanoparticles.
Catalysis
Chemical catalysis benefits especially from nanoparticles, due to the extremely large surface to volume ratio. The application potential of nanoparticles in catalysis ranges from fuel cell to catalytic converters and photocatalytic devices. Catalysis is also important for the production of chemicals.
Platinum nanoparticles are now being considered in the next generation of automotive catalytic converters because the very high surface area of nanoparticles could reduce the amount of platinum required. However, some concerns have been raised due to experiments demonstrating that they will spontaneously combust if methane is mixed with the ambient air. Ongoing research at the Centre National de la Recherche Scientifique (CNRS) in France may resolve their true usefulness for catalytic applications.[3] Nanofiltration may come to be an important application, although future research must be careful to investigate possible toxicity.
Filtration
A strong influence of nanochemistry on waste-water treatment, air purification and energy storage devices is to be expected. Mechanical or chemical methods can be used for effective filtration techniques. One class of filtration techniques is based on the use of membranes with suitable hole sizes, whereby the liquid is pressed through the membrane. Nanoporous membranes are suitable for a mechanical filtration with extremely small pores smaller than 10 nm ("nanofiltration") and may be composed of nanotubes. Nanofiltration is mainly used for the removal of ions or the separation of different fluids. On a larger scale, the membrane filtration technique is named ultrafiltration, which works down to between 10 and 100 nm. One important field of application for ultrafiltration is medical purposes as can be found in renal dialysis. Magnetic nanoparticles offer an effective and reliable method to remove heavy metal contaminants from waste water by making use of magnetic separation techniques. Using nanoscale particles increases the efficiency to absorb the contaminants and is comparatively inexpensive compared to traditional precipitation and filtration methods.
Energy
Main article: Energy applications of nanotechnology
The most advanced nanotechnology projects related to energy are: storage, conversion, manufacturing improvements by reducing materials and process rates, energy saving (by better thermal insulation for example), and enhanced renewable energy sources.
Reduction of energy consumption
A reduction of energy consumption can be reached by better insulation systems, by the use of more efficient lighting or combustion systems, and by use of lighter and stronger materials in the transportation sector. Currently used light bulbs only convert approximately 5% of the electrical energy into light. Nanotechnological approaches like light-emitting diodes (LEDs) or quantum caged atoms (QCAs) could lead to a strong reduction of energy consumption for illumination.
Increasing the efficiency of energy production
The degree of efficiency of the internal combustion engine is about 30-40% at the moment. Nanotechnology could improve combustion by designing specific catalysts with maximized surface area.
Recycling of batteries
Because of the relatively low energy density of batteries the operating time is limited and a replacement or recharging is needed. The huge number of spent batteries and accumulators represent a disposal problem. The use of batteries with higher energy content or the use of rechargeable batteries or supercapacitors with higher rate of recharging using nanomaterials could be helpful for the battery disposal problem.
Information and communication
Current high-technology production processes are based on traditional top down strategies, where nanotechnology has already been introduced silently. The critical length scale of integrated circuits is already at the nanoscale (50 nm and below) regarding the gate length of transistors in CPUs or DRAM devices.
Memory Storage
Electronic memory designs in the past have largely relied on the formation of transistors however research into crossbar switch based electronics have offered an alternative using reconfigurable interconnections between vertical and horizontal wiring arrays to create ultra high density memories. Two leaders in this area are Nantero which has developed a carbon nanotube based crossbar memory called Nano-RAM and Hewlett-Packard which has proposed the use of memristor material as a future replacement of Flash memory.
Novel semiconductor devices
An example of such novel devices is based on spintronics.The dependence of the resistance of a material (due to the spin of the electrons) on an external field is called magnetoresistance. This effect can be significantly amplified (GMR - Giant Magneto-Resistance) for nanosized objects, for example when two ferromagnetic layers are separated by a nonmagnetic layer, which is several nanometers thick (e.g. Co-Cu-Co). The GMR effect has led to a strong increase in the data storage density of hard disks and made the gigabyte range possible. The so called tunneling magnetoresistance (TMR) is very similar to GMR and based on the spin dependent tunneling of electrons through adjacent ferromagnetic layers. Both GMR and TMR effects can be used to create a non-volatile main memory for computers, such as the so called magnetic random access memory or MRAM.
Novel optoelectronic devices
In the modern communication technology traditional analog electrical devices are increasingly replaced by optical or optoelectronic devices due to their enormous bandwidth and capacity, respectively. Two promising examples are photonic crystals and quantum dots. Photonic crystals are materials with a periodic variation in the refractive index with a lattice constant that is half the wavelength of the light used. They offer a selectable band gap for the propagation of a certain wavelength, thus they resemble a semiconductor, but for light or photons instead of electrons. Quantum dots are nanoscaled objects, which can be used, among many other things, for the construction of lasers. The advantage of a quantum dot laser over the traditional semiconductor laser is that their emitted wavelength depends on the diameter of the dot. Quantum dot lasers are cheaper and offer a higher beam quality than conventional laser diodes.
Displays
The production of displays with low energy consumption could be accomplished using carbon nanotubes (CNT). Carbon nanotubes are electrically conductive and due to their small diameter of several nanometers, they can be used as field emitters with extremely high efficiency for field emission displays (FED). The principle of operation resembles that of the cathode ray tube, but on a much smaller length scale.
Quantum computers
Entirely new approaches for computing exploit the laws of quantum mechanics for novel quantum computers, which enable the use of fast quantum algorithms. The Quantum computer has quantum bit memory space termed "Qubit" for several computations at the same time. This facility may improve the performance of the older systems.
Heavy Industry
In inevitable use of nanotechnology will be in heavy industry.
Aerospace
Lighter and stronger materials will be of immense use to aircraft manufacturers, leading to increased performance. Spacecraft will also benefit, where weight is a major factor. Nanotechnology would help to reduce the size of equipment and thereby decrease fuel-consumption required to get it airborne.
Construction
Nanotechnology has the potential to make construction faster, cheaper, safer, and more varied. Automation of nanotechnology construction can allow for the creation of structures from advanced homes to massive skyscrapers much more quickly and at much lower cost.
Refineries
Using nanotech applications, refineries producing materials such as steel and aluminium will be able to remove any impurities in the materials they create.
Vehicle manufacturers
Much like aerospace, lighter and stronger materials will be useful for creating vehicles that are both faster and safer. Combustion engines will also benefit from parts that are more hard-wearing and more heat-resistant.
Consumer goods
Nanotechnology is already impacting the field of consumer goods, providing products with novel functions ranging from easy-to-clean to scratch-resistant. Modern textiles are wrinkle-resistant and stain-repellent; in the mid-term clothes will become "smart", through embedded "wearable electronics". Already in use are different nanoparticle improved products. Especially in the field of cosmetics, such novel products have a promising potential.
Foods
Nanotechnology can be applied in the production, processing, safety and packaging of food. A nanocomposite coating process could improve food packaging by placing anti-microbial agents directly on the surface of the coated film. Nanocomposites could increase or decrease gas permeability of different fillers as is needed for different products. They can also improve the mechanical and heat-resistance properties and lower the oxygen transmission rate. Research is being performed to apply nanotechnology to the detection of chemical and biological substances for sensing biochemical changes in foods.
Nano-foods
New consumer products created through nanotechnology are coming on the market at the rate of 3 to 4 per week, according to an advocacy group, The Project on Emerging Nanotechnologies (PEN), based on an inventory it has drawn up of 609 known or claimed nano-products.
On PEN's list are three foods -- a brand of canola cooking oil called Canola Active Oil, a tea called Nanotea and a chocolate diet shake called Nanoceuticals Slim Shake Chocolate.
Household
The most prominent application of nanotechnology in the household is self-cleaning or "easy-to-clean" surfaces on ceramics or glasses. Nanoceramic particles have improved the smoothness and heat resistance of common household equipment such as the flat iron.
Optics
The first sunglasses using protective and anti-reflective ultrathin polymer coatings are on the market. For optics, nanotechnology also offers scratch resistant surface coatings based on nanocomposites. Nano-optics could allow for an increase in precision of pupil repair and other types of laser eye surgery.
Textiles
The use of engineered nanofibers already makes clothes water- and stain-repellent or wrinkle-free. Textiles with a nanotechnological finish can be washed less frequently and at lower temperatures. Nanotechnology has been used to integrate tiny carbon particles membrane and guarantee full-surface protection from electrostatic charges for the wearer. Many other applications have been developed by research institutions such as the Textiles Nanotechnology Laboratory at Cornell University
Cosmetics
One field of application is in sunscreens. The traditional chemical UV protection approach suffers from its poor long-term stability. A sunscreen based on mineral nanoparticles such as titanium dioxide offer several advantages. Titanium oxide nanoparticles have a comparable UV protection property as the bulk material, but lose the cosmetically undesirable whitening as the particle size is decreased.
Agriculture
Applications of nanotechnology have the potential to change the entire agriculture sector and food industry chain from production to conservation, processing, packaging, transportation, and even waste treatment. Strategic applications of Nano Science can do wonders in the agriculture scenario. NanoScience concepts and Nanotechnology applications have the potential to redesign the production cycle, restructure the processing and conservation processes and redefine the food habits of the people.